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A high-performance recycling solution for polystyrene achieved by the synthesis of renewable poly(thioether) networks derived from D-limonene.

ABSTRACT: Nanocomposite polymers are prepared using a new sustainable materials synthesis process in which d-Limonene functions simultaneously both as a solvent for recycling polystyrene (PS) waste and as a monomer that undergoes UV-catalyzed thiol-ene polymerization reactions with polythiol comonomers to afford polymeric products composed of precipitated PS phases dispersed throughout elastomeric poly(thioether) networks. These blended networks exhibit mechanical properties that greatly exceed those of either polystyrene or the poly(thioether) network homopolymers alone.

SUBMITTER: Hearon K

PROVIDER: S-EPMC4000729 | biostudies-literature | 2014 Mar

REPOSITORIES: biostudies-literature

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A high-performance recycling solution for polystyrene achieved by the synthesis of renewable poly(thioether) networks derived from D-limonene.

Hearon Keith K Nash Landon D LD Rodriguez Jennifer N JN Lonnecker Alexander T AT Raymond Jeffery E JE Wilson Thomas S TS Wooley Karen L KL Maitland Duncan J DJ

Advanced materials (Deerfield Beach, Fla.) 20131119 10

Nanocomposite polymers are prepared using a new sustainable materials synthesis process in which d-Limonene functions simultaneously both as a solvent for recycling polystyrene (PS) waste and as a monomer that undergoes UV-catalyzed thiol-ene polymerization reactions with polythiol comonomers to afford polymeric products composed of precipitated PS phases dispersed throughout elastomeric poly(thioether) networks. These blended networks exhibit mechanical properties that greatly exceed those of e ...[more]

PMID: 24249666

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