Ontology highlight
ABSTRACT:
SUBMITTER: Bao H
PROVIDER: S-EPMC4038264 | biostudies-literature | 2014 Feb
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20140123 6
New advances in the functionalization of unactivated olefins with carbon nucleophiles have provided more efficient and practical approaches to convert inexpensive starting materials into valuable products. Recent examples have been reported with stabilized carbon nucleophiles, tethered carbon nucleophiles, diazoesters, and trifluoromethane donors. A general method for functionalizing olefins with aromatic, aliphatic, and vinyl Grignard reagents was developed. In a one-pot process, olefins are ox ...[more]