Ontology highlight
ABSTRACT:
SUBMITTER: Maity S
PROVIDER: S-EPMC5618772 | biostudies-literature | 2017 Jul
REPOSITORIES: biostudies-literature
Chemical science 20170516 7
Unactivated acyclic internal aliphatic olefins are often found to be unreactive in conventional alkenylation reactions. To address this problem, a cobalt catalyzed allylic selective dehydrogenative Heck reaction with internal aliphatic olefins has been developed. The method is highly regio- and stereoselective, the conditions are mild and a wide variety of functional groups can be tolerated. Remarkably, both internal and terminal aliphatic olefins can be employed, thereby significantly expanding ...[more]