Baeyer-Villiger Rearrangement of a Substituted Pyrrole by Oxone.
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ABSTRACT:
SUBMITTER: Kao JP
PROVIDER: S-EPMC4041875 | biostudies-literature | 2014 May
REPOSITORIES: biostudies-literature
Publications
Baeyer-Villiger Rearrangement of a Substituted Pyrrole by Oxone.
Kao Joseph P Y JP Muralidharan Sukumaran S Zavalij Peter Y PY Fletcher Steven S Xue Fengtian F Rosen Gerald M GM
Tetrahedron letters 20140501 19
Pyrroloxyls have been reported to exhibit very narrow EPR spectral lines, essential for <i>in vivo</i> imaging. En route to pyrroloxyls, we observed an unexpected Baeyer-Villiger rearrangement, leading to loss of aromaticity and formation of a 4,5-dihydro-1<i>H</i>-ketopyrrole. ...[more]
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