Unknown

Dataset Information

0

Ligand-enabled γ-C-H olefination and carbonylation: construction of β-quaternary carbon centers.

ABSTRACT: Monoselective γ-C-H olefination and carbonylation of aliphatic acids has been accomplished by using a combination of a quinoline-based ligand and a weakly coordinating amide directing group. The reaction provides a new route for constructing richly functionalized all-carbon quaternary carbon centers at the β-position of aliphatic acids.

SUBMITTER: Li S 

PROVIDER: S-EPMC4049142 | biostudies-literature |

REPOSITORIES: biostudies-literature

Json Xml

Similar Datasets

Unknown Stereocontrolled alkylative construction of quaternary carbon centers.
| S-EPMC2666470 | biostudies-literature
Unknown Lewis Acid Catalyzed Transfer Hydromethallylation for the Construction of Quaternary Carbon Centers.
| S-EPMC6856816 | biostudies-literature
Unknown Ligand-Enabled ?-C(sp3 )-H Olefination of Free Carboxylic Acids.
| S-EPMC7496353 | biostudies-literature
Unknown Highly Diastereoselective Construction of Carbon- Heteroatom Quaternary Stereogenic Centers in the Synthesis of Analogs of Bioactive Compounds: From Monofluorinated Epoxyalkylphosphonates to α-Fluoro-, β-, or γ-Amino Alcohol Derivatives of Alkylphosphonates.
| S-EPMC8208234 | biostudies-literature
Unknown Synthesis of quaternary carbon centers via hydroformylation.
| S-EPMC2928406 | biostudies-literature
Unknown Enantioselective construction of all-carbon quaternary centers by branch-selective Pd-catalyzed allyl-allyl cross-coupling.
| S-EPMC3131072 | biostudies-other
Unknown Ligand-enabled ortho-C-H olefination of phenylacetic amides with unactivated alkenes.
| S-EPMC5887099 | biostudies-literature
Unknown Migratory functionalization of unactivated alkyl bromides for construction of all-carbon quaternary centers via transposed tert-C-radicals.
| S-EPMC7519689 | biostudies-literature
Unknown Radical 1,2,3-tricarbofunctionalization of α-vinyl-β-ketoesters enabled by a carbon shift from an all-carbon quaternary center.
| S-EPMC9200052 | biostudies-literature
Unknown Catalytic Cyclopropanol Ring Opening for Divergent Syntheses of γ-Butyrolactones and δ-Ketoesters Containing All-Carbon Quaternary Centers.
| S-EPMC8389773 | biostudies-literature