Ontology highlight
ABSTRACT:
SUBMITTER: Chakraborty S
PROVIDER: S-EPMC4077457 | biostudies-literature | 2014
REPOSITORIES: biostudies-literature
Chakraborty Sourav S Mondal Snehasish S Kumari Rina R Bhowmick Sourav S Das Prolay P Das Neeladri N
Beilstein journal of organic chemistry 20140605
A facile and efficient synthesis of a new series of triptycene-based tripods is being reported. Using 2,6,14- or 2,7,14-triaminotriptycenes as synthons, the corresponding triazidotriptycenes were prepared in high yield. Additionally, we report the transformation of 2,6,14- or 2,7,14-triaminotriptycenes to the corresponding ethynyl-substituted triptycenes via their tribromo derivatives. Subsequently, derivatization of ethynyl-substituted triptycenes was studied to yield the respective propiolic a ...[more]