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(5-n-Butyl-10,20-diiso-butyl-porphyrin-ato)nickel(II).

ABSTRACT: The asymmetric unit of the title compound, [Ni(C32H36N4)], contains two independent mol-ecules exhibiting an overall ruffled conformation of the porphyrin macrocycle and differing mainly in the positions of the methyl groups. The average Ni-N bond lengths are 1.912?(2) and 1.910?(2)?Å in the two mol-ecules. The mol-ecules form a closely spaced lattice structure in which neighbouring porphyrins are oriented in a nearly perpendicular fashion to each other. The compound was prepared via nucleophilic substitution of (5,15-diiso-butyl-porphyrinato)nickel(II) with n-butyl-lithium.

SUBMITTER: Senge MO

PROVIDER: S-EPMC4120589 | biostudies-literature | 2014 Jul

REPOSITORIES: biostudies-literature

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(5-n-Butyl-10,20-diiso-butyl-porphyrin-ato)nickel(II).

Senge Mathias O MO Dahms Katja K

Acta crystallographica. Section E, Structure reports online 20140607 Pt 7

The asymmetric unit of the title compound, [Ni(C32H36N4)], contains two independent mol-ecules exhibiting an overall ruffled conformation of the porphyrin macrocycle and differing mainly in the positions of the methyl groups. The average Ni-N bond lengths are 1.912 (2) and 1.910 (2) Å in the two mol-ecules. The mol-ecules form a closely spaced lattice structure in which neighbouring porphyrins are oriented in a nearly perpendicular fashion to each other. The compound was prepared via nucleophili ...[more]

PMID: 25161518

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