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(?(6)-Benzene)(carbonato-?(2) O,O')[di-cyclohex-yl(naphthalen-1-ylmeth-yl)phosphane-?P]ruthenium(II) chloro-form tris-olvate.

ABSTRACT: The title compound, [Ru(CO3)(?(6)-C6H6){(C6H11)2P(CH2C10H7)}]·3CHCl3, was synthesized by carbonation of [RuCl2(?(6)-C6H6){(C6H11)2P(CH2C10H7)}] with NaHCO3 in methanol at room temperature. The Ru(II) atom is surrounded by a benzene ligand, a chelating carbonate group and a phosphane ligand in a piano-stool configuration. The crystal packing is consolidated by C-H?O and C-H?Cl hydrogen-bonding inter-actions between adjacent metal complexes and between the complexes and the solvent mol-ecules. The asymmetric unit contains one metal complex and three chloro-form solvent mol-ecules of which only one was modelled. The estimated diffraction contributions of the other two strongly disordered chloro-form solvent mol-ecules were substracted from the observed diffraction data using the SQUEEZE procedure in PLATON [Spek (2009 ?). Acta Cryst. D65, 148-155].

SUBMITTER: Gowrisankar S 

PROVIDER: S-EPMC4120604 | biostudies-literature | 2014 Jul

REPOSITORIES: biostudies-literature

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(η(6)-Benzene)(carbonato-κ(2) O,O')[di-cyclohex-yl(naphthalen-1-ylmeth-yl)phosphane-κP]ruthenium(II) chloro-form tris-olvate.

Gowrisankar Saravanan S   Neumann Helfried H   Spannenberg Anke A   Beller Matthias M  

Acta crystallographica. Section E, Structure reports online 20140621 Pt 7

The title compound, [Ru(CO3)(η(6)-C6H6){(C6H11)2P(CH2C10H7)}]·3CHCl3, was synthesized by carbonation of [RuCl2(η(6)-C6H6){(C6H11)2P(CH2C10H7)}] with NaHCO3 in methanol at room temperature. The Ru(II) atom is surrounded by a benzene ligand, a chelating carbonate group and a phosphane ligand in a piano-stool configuration. The crystal packing is consolidated by C-H⋯O and C-H⋯Cl hydrogen-bonding inter-actions between adjacent metal complexes and between the complexes and the solvent mol-ecules. The  ...[more]

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