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Catena-Poly[[trans-bis-(1,3-benzo-thia-zole-?N)manganese(II)]-di-?-chlorido].

ABSTRACT: In the title coordination polymer, [MnCl2(C7H5NS)2] n , the Mn(II) ion is located on the inter-section of a twofold rotation axis and a mirror plane and adopts an octa-hedral coordination geometry defined by two mutually trans N atoms from benzo-thia-zole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layers parallel to (001) featuring ?-? stacking inter-actions with a centroid-centroid distance of 3.6029?(15)?Å.

SUBMITTER: Bouchareb H

PROVIDER: S-EPMC4120608 | biostudies-literature | 2014 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[trans-bis-(1,3-benzo-thia-zole-κN)manganese(II)]-di-μ-chlorido].

Bouchareb Hasna H Benmebarek Sabrina S Bouacida Sofiane S Merazig Hocine H Boudraa Mhamed M

Acta crystallographica. Section E, Structure reports online 20140621 Pt 7

In the title coordination polymer, [MnCl2(C7H5NS)2] n , the Mn(II) ion is located on the inter-section of a twofold rotation axis and a mirror plane and adopts an octa-hedral coordination geometry defined by two mutually trans N atoms from benzo-thia-zole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The Mn(II) ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layer ...[more]

PMID: 25161533

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catena-Poly[bis(1,3-benzo-thia-zol-3-ium) [[di-chlorido-anti-monate(III)]-di-μ-chlorido-μ-oxido-[chlorido-anti-monate(III)]-μ-chlorido]].

Project description:The title compound, {(C7H6NS)2[Sb2Cl6O]} n , contains two benzo-thia-zolidium cations and one tri-μ-chlorido-tri-chlorido-μ-oxido-di-anti-monate(III) anion. The structure of the inorganic cation may be described as as being built up from two polyhedra, i.e. a square-pyramidal SbCl4O and a distorted octa-hedral SbOCl5 unit, sharing a common face (comprising the O atom and two Cl atoms). The two benzo-thia-zole cations are quasi-planar and subtend a dihedral angle of 19.93 (5)°. The crystal packing can be described by alternating (100) layers and [001] chains of the organic cations and inorganic anions connected through an extensive three-dimensional network of N-H⋯Cl, C-H⋯O and C-H⋯Cl hydrogen bonds. This is consolidated by slipped π-π stacking, with centroid-to-centroid distances between the benzo-thia-zole rings of 3.7111 (18)-3.8452 (16) Å. These inter-actions link the mol-ecules within the layers and also link the layers together and reinforce the cohesion of the ionic structure.

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Crystal structure of catena-poly[1,3-di-benzyl-benzimidazolium [[chlorido-mercurate(II)]-di-?-chlorido]].

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6-Bromo-2-methyl-sulfanyl-1,3-benzo-thia-zole.

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catena-Poly[(dichloridocadmium)-di-?-chlorido-[bis-(morpholinium-?O)cadmium]-di-?-chlorido].

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