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Catena-Poly[cobalt(II)-di-?-chlorido-?Cl:Cl-?-1,5-dimethyl-1H-tetra-zole-?N:N]: an X-ray powder investigation.

ABSTRACT: The asymmetric unit of the title compound, [CoCl(2)(C(3)H(6)N(4))](n), contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethyl-tetra-zole ligand. The coordination polyhedra of both Co atoms adopt flattened octa-hedral geometry, with two N atoms from two ligands in axial positions and four Cl atoms in equatorial sites. Neighbouring Co atoms are linked together via two bridging Cl atoms and one tetra-zole ring to form polymeric chains running along the a axis.

SUBMITTER: Ivashkevich LS

PROVIDER: S-EPMC2968201 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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catena-Poly[cobalt(II)-di-μ-chlorido-κCl:Cl-μ-1,5-dimethyl-1H-tetra-zole-κN:N]: an X-ray powder investigation.

Ivashkevich Ludmila S LS Lyakhov Alexander S AS Mosalkova Anastasiya P AP Gaponik Pavel N PN Ivashkevich Oleg A OA

Acta crystallographica. Section E, Structure reports online 20090128 Pt 2

The asymmetric unit of the title compound, [CoCl(2)(C(3)H(6)N(4))](n), contains two Co atoms, both lying on inversion centres, two Cl atoms and one 1,5-dimethyl-tetra-zole ligand. The coordination polyhedra of both Co atoms adopt flattened octa-hedral geometry, with two N atoms from two ligands in axial positions and four Cl atoms in equatorial sites. Neighbouring Co atoms are linked together via two bridging Cl atoms and one tetra-zole ring to form polymeric chains running along the a axis. ...[more]

PMID: 21581826

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