Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper-nitrene complexes.
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ABSTRACT:
SUBMITTER: Abram SL
PROVIDER: S-EPMC4149874 | biostudies-literature | 2014 Sep
REPOSITORIES: biostudies-literature
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Evidence of two-state reactivity in alkane hydroxylation by Lewis-acid bound copper-nitrene complexes.
Abram Sarah-Luise SL Monte-Pérez Inés I Pfaff Florian Felix FF Farquhar Erik R ER Ray Kallol K
Chemical communications (Cambridge, England) 20140901 69
The behavior of the Lewis-acid adducts of two copper-nitrene [Cu(NR)](+) complexes in nitrene-transfer and H-atom abstraction reactions have been demonstrated to depend on the nature of the nitrene substituents. Two-state reactivity, in which a singlet ground state and a nearby triplet excited-state both contribute, provides a useful model for interpreting reactivity trends of the two compounds. ...[more]
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