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ABSTRACT:
SUBMITTER: Comba P
PROVIDER: S-EPMC3294187 | biostudies-literature | 2012 Mar
REPOSITORIES: biostudies-literature
Comba Peter P Haaf Christina C Helmle Stefan S Karlin Kenneth D KD Pandian Shanthi S Waleska Arkadius A
Inorganic chemistry 20120214 5
The reactivity of copper complexes of three different second-generation bispidine-based ligands (bispidine = 3,7-diazabicyclo[3.3.1]nonane; mono- and bis-tetradentate; exclusively tertiary amine donors) with dioxygen [(reversible) binding of dioxygen by copper(I)] is reported. The UV-vis, electrospray ionization mass spectrometry, electron paramagnetic resonance, and vibrational spectra (resonance Raman) of the dioxygen adducts indicate that, depending on the ligand and reaction conditions, seve ...[more]