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A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states.

ABSTRACT: The amido ligand -N(Si(i)Pr3)DIPP (DIPP = 2,6-diisopropylphenyl) has been used to prepare two-coordinate complexes of Cr(I), Cr(II), and Cr(III). The two-coordinate Cr(II) complex has also been used to prepare a three-coordinate Cr(III) iodide complex, which can be used to access a stable Cr(III) methyl species.

SUBMITTER: Cai IC

PROVIDER: S-EPMC4184985 | biostudies-literature | 2014 Nov

REPOSITORIES: biostudies-literature

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A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states.

Cai Irene C IC Lipschutz Michael I MI Tilley T Don TD

Chemical communications (Cambridge, England) 20141101 86

The amido ligand -N(Si(i)Pr3)DIPP (DIPP = 2,6-diisopropylphenyl) has been used to prepare two-coordinate complexes of Cr(I), Cr(II), and Cr(III). The two-coordinate Cr(II) complex has also been used to prepare a three-coordinate Cr(III) iodide complex, which can be used to access a stable Cr(III) methyl species. ...[more]

PMID: 25222516

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