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Phenyl bis-(morpholin-4-yl-amido)-phosphinate.

ABSTRACT: In the title compound, C(14)H(23)N(4)O(4)P, the P atom is in a distorted tetra-hedral environment with bond angles in the range 96.87?(6)-119.86?(6)°. The two morpholinyl groups adopt a chair conformation. The phenyl ring is disordered over two sets of sites with equal occupancies [0.500?(2)]. In the crystal, adjacent mol-ecules are linked via N-H?O hydrogen bonds into an extended chain running parallel to the a axis. Only one of the amidate N-H groups is involved in hydrogen bonding.

SUBMITTER: Pourayoubi M

PROVIDER: S-EPMC3213632 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Phenyl bis-(morpholin-4-yl-amido)-phosphinate.

Pourayoubi Mehrdad M Eshtiagh-Hosseini Hossein H Negari Monireh M Nečas Marek M

Acta crystallographica. Section E, Structure reports online 20110730 Pt 8

In the title compound, C(14)H(23)N(4)O(4)P, the P atom is in a distorted tetra-hedral environment with bond angles in the range 96.87 (6)-119.86 (6)°. The two morpholinyl groups adopt a chair conformation. The phenyl ring is disordered over two sets of sites with equal occupancies [0.500 (2)]. In the crystal, adjacent mol-ecules are linked via N-H⋯O hydrogen bonds into an extended chain running parallel to the a axis. Only one of the amidate N-H groups is involved in hydrogen bonding. ...[more]

PMID: 22091209

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