Ontology highlight
ABSTRACT:
SUBMITTER: Chen M
PROVIDER: S-EPMC4214550 | biostudies-literature | 2014 Nov
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20140915 45
Reported herein is the iridium-catalyzed regio- and enantioselective allylic substitution reactions of unstabilized silyl dienolates derived from dioxinones. Asymmetric allylic substitution of a variety of allylic trichloroethyl carbonates with these silyl dienolates gave γ-allylated products selectively in 60-84% yield and 90-98% ee. ...[more]