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Triptycene induced enhancement of membrane gas selectivity for microporous Troger's base polymers.


ABSTRACT: A highly gas permeable polymer with exceptional size selectivity is prepared by fusing triptycene units together via a poly-merization reaction involving Tröger's base formation. The extreme rigidity of this polymer of intrinsic microporosity (PIM-Trip-TB) facilitates gas permeability data that lie well above the benchmark 2008 Robeson upper bounds for the important O2 /N2 and H2 /N2 gas pairs.

SUBMITTER: Carta M 

PROVIDER: S-EPMC4223990 | biostudies-literature |

REPOSITORIES: biostudies-literature

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