Dataset Information
Z-Selective Ruthenium Metathesis Catalysts: Comparison of Nitrate and Nitrite X-type Ligands.
Ontology highlight
ABSTRACT:
SUBMITTER: Pribisko MA
PROVIDER: S-EPMC4254782 | biostudies-literature | 2014 Dec
REPOSITORIES: biostudies-literature
Publications
<i>Z</i>-Selective Ruthenium Metathesis Catalysts: Comparison of Nitrate and Nitrite X-type Ligands.
Polyhedron 20141201
Two new Ru-based metathesis catalysts, <b>3</b> and <b>4</b>, have been synthesized for the purpose of comparing their catalytic properties to those of their <i>cis</i>-selective nitrate analogues, <b>1</b> and <b>2</b>. Although catalysts <b>3</b> and <b>4</b> exhibited slower initiation rates than <b>1</b> and <b>2</b>, they maintained high <i>cis</i>-selectivity in homodimerization and ring-opening metathesis polymerization reactions. Furthermore, the nitrite catalysts displayed higher <i>cis ...[more]