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Crystal structure of bromido-bis-(naph-thal-en-1-yl)anti-mony(III).

ABSTRACT: In the title compound, [SbBr(C10H7)2], the Sb(III) atom has a distorted trigonal-pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26?(18)°. An intra-molecular C-H?Br hydrogen bond forms an S(5) ring motif. In the crystal, weak C-H?Br inter-actions link the mol-ecules into helical chains along the b-axis direction.

SUBMITTER: Shawkataly OB

PROVIDER: S-EPMC4257233 | biostudies-literature | 2014 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of bromido-bis-(naph-thal-en-1-yl)anti-mony(III).

Shawkataly Omar Bin OB Hussien Abdelnasir Hafiz Malik HM Rosli Mohd Mustaqim MM

Acta crystallographica. Section E, Structure reports online 20140924 Pt 10

In the title compound, [SbBr(C10H7)2], the Sb(III) atom has a distorted trigonal-pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26 (18)°. An intra-molecular C-H⋯Br hydrogen bond forms an S(5) ring motif. In the crystal, weak C-H⋯Br inter-actions link the mol-ecules into helical chains along the b-axis direction. ...[more]

PMID: 25484676

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