Browse
Submit Data
Databases
API
Help

Dataset Information

11 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dichloridotriphenyl-anti-mony(V)-bis-(pyrrolidin-1-ylthio-carbon-yl) disulfide (1/1).

ABSTRACT: The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)Cl(2)]·C(10)H(16)N(2)S(4), comprises a bis-(pyrrolidinylthio-carbamo-yl) mol-ecule and a dichloro-triphenyl-anti-mony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thio-carbamoyl units, connected via the disulfide bond, are approximately perpendicular to each other. The mol-ecules are connected by weak C-H?S and C-H?Cl hydrogen-bonding inter-actions into two one-dimensional supra-molecular chains.

SUBMITTER: Quan L

PROVIDER: S-EPMC2915061 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dichloridotriphenyl-anti-mony(V)-bis-(pyrrolidin-1-ylthio-carbon-yl) disulfide (1/1).

Quan Li L Yin Handong H Zhai Jun J Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)Cl(2)]·C(10)H(16)N(2)S(4), comprises a bis-(pyrrolidinylthio-carbamo-yl) mol-ecule and a dichloro-triphenyl-anti-mony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thio-carbamoyl units, connected via the disulfide bond, are approximately perpendicular to each other. The mol-ecules are connected by weak ...[more]

PMID: 21200467

Similar Datasets

Triphenyl-bis[4-(trifluoro-meth-yl)benzoato-?O]anti-mony(V).

Project description:The title complex, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The environment of the Sb atom approximates a trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 4-(trifluoro-meth-yl)benzoate ligands. In this ligand, the CF(3) group is disordered by rotation about the C-C bond and the F atoms are distributed over two sets of sites with occupancies of 0.62?(3) and 0.38?(3). In the crystal, mol-ecules are assembled in a three-dimensional framework through weak C-H?O hydrogen bonds.

| S-EPMC2969530 | biostudies-literature

Crystal structure of bromido-bis-(naph-thal-en-1-yl)anti-mony(III).

Project description:In the title compound, [SbBr(C10H7)2], the Sb(III) atom has a distorted trigonal-pyramidal coordination geometry and the planes of the two naphthalene ring systems make a dihedral angle of 80.26?(18)°. An intra-molecular C-H?Br hydrogen bond forms an S(5) ring motif. In the crystal, weak C-H?Br inter-actions link the mol-ecules into helical chains along the b-axis direction.

| S-EPMC4257233 | biostudies-literature

?-Oxido-bis-[(chloro-acetato-?O)-triphenyl-anti-mony(V)].

Project description:The Sb atom in the centrosymmetric title complex, [Sb(2)(C(6)H(5))(6)(C(2)H(2)ClO(2))(2)O], has a distorted trigonal-bipyramidal geometry. The bridging oxide O atom occupies one of the axial sites, while the O atom of the chloroacetate ligand occupies the other.

| S-EPMC2960346 | biostudies-literature

4-Methyl-2,6-bis-(pyrrolidin-1-yl)pyrimidine.

Project description:In the crystal of the title compound, C13H20N4, the mol-ecule is nearly planar, the dihedral angles between the pyrimidine and the two pyrrolidine rings being 4.71?(2) and 4.50?(2)°. The crystal features inversion-related dimers linked by pairs of C-H?N hydrogen bonds generating R2(2)(16) patterns. The dimeric units are further linked into C(6) chains via an additional C-H?N hydrogen bond.

| S-EPMC3589020 | biostudies-literature

Chloridobis{2-[(dimethyl-amino)-meth-yl]phen-yl}anti-mony(III).

Project description:In the title compound, [Sb(C(9)H(12)N)(2)Cl], the Sb atom adopts a Ψ-trigonal-bipyramidal geometry. The two 2-[(dimethyl-amino)-methyl]-phenyl ligands are coordinated asymmetrically to the Sb atom. The carbon atoms of one of the ligands are disordered over sets of sites with equal occupancy, resulting in two conformational isomers in the crystal. The Sb-C and Sb-N distances in the ordered ligand are: 2.153 (4) and 3.326 (5) Å, respectively. The corresponding distances in the disordered ligand are: 2.103 (5)/2.188 (5) and 2.454 (3) Å, respectively. The structure displays intra-molecular C-H⋯Cl hydrogen bonding.

| S-EPMC2970968 | biostudies-literature

Bis[(E)-3-(4-meth-oxy-phen-yl)prop-2-enoato]triphenyl-anti-mony(V) benzene monosolvate.

Project description:The asymmetric unit of the title compound, [Sb(C6H5)3(C10H9O3)2]·C6H6, contains one organometallic mol-ecule and one benzene mol-ecule that is disordered over two sets of sites with an occupancy ratio of 0.556?(15):0.444?(15). The Sb(V) atom is in a distorted trigonal-bipyramidal environment with the carboxyl-ate O atoms in axial positions and phenyl C atoms in the equatorial plane. As a result of additional Sb?O inter-actions, one of the C-Sb-C angles is widened to 140.19?(6)°.

| S-EPMC3588489 | biostudies-literature

Bis{[1-(tert-butoxy-carbonyl)-pyrrolidin-2-yl]meth-yl} carbonate.

Project description:The asymmetric unit of the title compound, C(21)H(36)N(2)O(7), consists of two independent half-mol-ecules, the other halves being generated by twofold rotational axes. The two independent half-mol-ecules are related by a pseudo-inversion center. In one, the pyrrolidine ring adopts a twist conformation whereas in the other it is in an envelope conformation. The crystal packing is stabilized by C-H?O hydrogen bonds.

| S-EPMC2971100 | biostudies-literature

Bis(pyrrolidin-1-yl)phosphinic (2,4-di-fluoro-benzo-yl)amide.

Project description:The P atom in the title mol-ecule, C(15)H(20)F(2)N(3)O(2)P, is in a distorted tetra-hedral P(O)(N)(N)(2) environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other. An F atom at position 2 and an H atom at position 6 are found to occupy similar sites in a 0.70:0.30 ratio and were refined with fixed occupancies. The pyrrolidin-1-yl rings are disordered over two sets of sites, with site occupancies of 0.566?(6) and 0.434?(6), and were refined using a two-part model. In the crystal, hydrogen-bonded dimers linked by pairs of N-H?O(P) hydrogen bonds generate an R(2) (2)(8) ring motif.

| S-EPMC3435709 | biostudies-literature

Bis(2-amino-4-chloro-benzoato)triphenyl-anti-mony(V).

Project description:The title complex mol-ecule, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], possesses crystallographically imposed C(2) symmetry. The Sb atom exhibits a trigonal-bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl-ate groups and the equatorial positions by the C atoms of the phenyl groups. Intra-molecular N-H?O and C-H?O hydrogen bonds occur.

| S-EPMC2971026 | biostudies-literature

Bis(2-hydroxy-benzaldehyde oximato-?O)triphenyl-anti-mony(V).

Project description:The mol-ecule of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The Sb center has a slightly distorted trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 2-hydroxy-benzaldehyde oximate ligands. An intra-molecular O-H?N inter-action is present. The crystal structure is stabilized by C-H?O inter-actions.

| S-EPMC2971330 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data