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Dichloridotriphenyl-anti-mony(V)-bis-(pyrrolidin-1-ylthio-carbon-yl) disulfide (1/1).

ABSTRACT: The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)Cl(2)]·C(10)H(16)N(2)S(4), comprises a bis-(pyrrolidinylthio-carbamo-yl) mol-ecule and a dichloro-triphenyl-anti-mony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thio-carbamoyl units, connected via the disulfide bond, are approximately perpendicular to each other. The mol-ecules are connected by weak C-H?S and C-H?Cl hydrogen-bonding inter-actions into two one-dimensional supra-molecular chains.

SUBMITTER: Quan L

PROVIDER: S-EPMC2915061 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Dichloridotriphenyl-anti-mony(V)-bis-(pyrrolidin-1-ylthio-carbon-yl) disulfide (1/1).

Quan Li L Yin Handong H Zhai Jun J Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

The asymmetric unit of the title compound, [Sb(C(6)H(5))(3)Cl(2)]·C(10)H(16)N(2)S(4), comprises a bis-(pyrrolidinylthio-carbamo-yl) mol-ecule and a dichloro-triphenyl-anti-mony(V) complex. In the Sb complex, the central atom is coordinated by three C atoms of the three phenyl ligands and two Cl atoms in a slightly distorted trigonal-bipyramidal geometry. The thio-carbamoyl units, connected via the disulfide bond, are approximately perpendicular to each other. The mol-ecules are connected by weak ...[more]

PMID: 21200467

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