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Crystal structure of 4-bromo-N-(2-hydroxy-phen-yl)benzamide.

ABSTRACT: In the title compound, C13H10BrNO2, the mean plane of the non-H atoms of the central amide C-N-C(=O)-C fragment (r.m.s. deviation = 0.004?Å) forms a dihedral angle of 73.97?(12)° with the hy-droxy-substituted benzene ring and 25.42?(19)° with the bromo-substituted benzene ring. The two aromatic rings are inclined to one another by 80.7?(2)°. In the crystal, mol-ecules are linked by O-H?O and N-H?O hydrogen bonds, forming chains along [010]. The chains are linked by weak C-H?O hydrogen bonds, forming sheets parallel to (100), and enclosing R (3) 3(17) and R (3) 2(9) ring motifs.

SUBMITTER: Moreno-Fuquen R

PROVIDER: S-EPMC4257397 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of 4-bromo-N-(2-hydroxy-phen-yl)benzamide.

Moreno-Fuquen Rodolfo R Melo Vanessa V Ellena Javier J

Acta crystallographica. Section E, Structure reports online 20141115 Pt 12

In the title compound, C13H10BrNO2, the mean plane of the non-H atoms of the central amide C-N-C(=O)-C fragment (r.m.s. deviation = 0.004 Å) forms a dihedral angle of 73.97 (12)° with the hy-droxy-substituted benzene ring and 25.42 (19)° with the bromo-substituted benzene ring. The two aromatic rings are inclined to one another by 80.7 (2)°. In the crystal, mol-ecules are linked by O-H⋯O and N-H⋯O hydrogen bonds, forming chains along [010]. The chains are linked by weak C-H⋯O hydrogen bonds, for ...[more]

PMID: 25553033

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