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Crystal structure of 4,6-bis-[(E)-4-bromo-styr-yl]-2-(butyl-sulfan-yl)pyrimidine.

ABSTRACT: In the title compound, C24H22Br2N2S, the dihedral angles between the central pyrimidine ring and the pendant bromo-benzene rings are 11.02?(11) and 13.20?(12)°. The butyl side chain adopts a gauche conformation [C-C-C-C = -67.4?(4)°]. In the crystal, weak aromatic ?-? stacking is observed between the pyrimidine ring and one of the benzene rings [centroid-centroid separation = 3.6718?(17)?Å].

SUBMITTER: Yu W

PROVIDER: S-EPMC4257452 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of 4,6-bis-[(E)-4-bromo-styr-yl]-2-(butyl-sulfan-yl)pyrimidine.

Yu Wang W Song Jingbao J Wang Aijian A

Acta crystallographica. Section E, Structure reports online 20141121 Pt 12

In the title compound, C24H22Br2N2S, the dihedral angles between the central pyrimidine ring and the pendant bromo-benzene rings are 11.02 (11) and 13.20 (12)°. The butyl side chain adopts a gauche conformation [C-C-C-C = -67.4 (4)°]. In the crystal, weak aromatic π-π stacking is observed between the pyrimidine ring and one of the benzene rings [centroid-centroid separation = 3.6718 (17) Å]. ...[more]

PMID: 25553047

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