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Silver-Mediated Synthesis of Indolizines via Oxidative C-H functionalization and 5- endo-dig cyclization.


ABSTRACT: An efficient strategy for the synthesis of indolizines from readily available starting materials via oxidative C-H functionalization and 5-endo-dig cyclization in one step has been demonstrated. This protocol represents wide substrate scope, high functional group tolerance and selectivity. The structure of the product was confirmed by the X-ray crystallographic studies. The Ag2CO3 required of this tandem reaction can be recycled and reused after undergoing oxidative reaction.

SUBMITTER: Pandya AN 

PROVIDER: S-EPMC4260338 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

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Silver-Mediated Synthesis of Indolizines via Oxidative C-H functionalization and <i>5- endo-dig</i> cyclization.

Pandya Amit N AN   Fletcher James T JT   Villa Eric M EM   Agrawal Devendra K DK  

Tetrahedron letters 20141201 50


An efficient strategy for the synthesis of indolizines from readily available starting materials via oxidative C-H functionalization and <i>5-endo-dig</i> cyclization in one step has been demonstrated. This protocol represents wide substrate scope, high functional group tolerance and selectivity. The structure of the product was confirmed by the X-ray crystallographic studies. The Ag<sub>2</sub>CO<sub>3</sub> required of this tandem reaction can be recycled and reused after undergoing oxidative  ...[more]

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