Unknown

Dataset Information

0

Pt-catalyzed cyclization/1,2-migration for the synthesis of indolizines, pyrrolones, and indolizinones.

ABSTRACT: Indolizine, pyrrolone, and indolizinone heterocycles are easily accessed via the Pt(II)-catalyzed cycloisomerization or a tandem cyclization/1,2-migration of pyridine propargylic alcohols and derivatives. This method provides an efficient synthesis of highly functionalized heterocycles from readily available substrates. [reaction: see text]

SUBMITTER: Smith CR 

PROVIDER: S-EPMC3384527 | biostudies-other | 2007 Mar

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Pt-catalyzed cyclization/1,2-migration for the synthesis of indolizines, pyrrolones, and indolizinones.

Smith Cameron R CR   Bunnelle Eric M EM   Rhodes Allison J AJ   Sarpong Richmond R  

Organic letters 20070220 6

Indolizine, pyrrolone, and indolizinone heterocycles are easily accessed via the Pt(II)-catalyzed cycloisomerization or a tandem cyclization/1,2-migration of pyridine propargylic alcohols and derivatives. This method provides an efficient synthesis of highly functionalized heterocycles from readily available substrates. [reaction: see text] ...[more]

Similar Datasets

Unknown Pt-catalyzed cyclization/migration of propargylic alcohols for the synthesis of 3(2H)-furanones, pyrrolones, indolizines, and indolizinones.
| S-EPMC3351138 | biostudies-literature
Unknown Pt(II)-catalyzed synthesis of 1,2-dihydropyridines from aziridinyl propargylic esters.
| S-EPMC3384524 | biostudies-literature
Unknown Palladium(II)-catalyzed cyclization of unsaturated hydroperoxides for the synthesis of 1,2-dioxanes.
| S-EPMC2757105 | biostudies-literature
Unknown Modular Synthesis of 1,2-Diamine Derivatives via Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides.
| S-EPMC2996102 | biostudies-literature
Unknown Cu(II)-catalyzed olefin migration and Prins cyclization: highly diastereoselective synthesis of substituted tetrahydropyrans.
| S-EPMC3155620 | biostudies-literature
Unknown Iridium-catalyzed arylative cyclization of alkynones by 1,4-iridium migration.
| S-EPMC4464530 | biostudies-literature
Unknown Copper-Catalyzed Dual Cyclization for the Synthesis of Quinindolines.
| S-EPMC7696892 | biostudies-literature
Unknown I(III)-Catalyzed Oxidative Cyclization-Migration Tandem Reactions of Unactivated Anilines.
| S-EPMC8135073 | biostudies-literature
Unknown Palladium-catalyzed carbonylative cyclization/arylation cascade for 2-aroylindolizine synthesis.
| S-EPMC3582654 | biostudies-literature
Unknown Enantioselective Copper-Catalyzed Borylative Cyclization for the Synthesis of Quinazolinones.
| S-EPMC8252434 | biostudies-literature