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Synthesis of ordered mesoporous phenanthrenequinone-carbon via ?-? interaction-dependent vapor pressure for rechargeable batteries.

ABSTRACT: The ?-? interaction-dependent vapour pressure of phenanthrenequinone can be used to synthesize a phenanthrenequinone-confined ordered mesoporous carbon. Intimate contact between the insulating phenanthrenequinone and the conductive carbon framework improves the electrical conductivity. This enables a more complete redox reaction take place. The confinement of the phenanthrenequinone in the mesoporous carbon mitigates the diffusion of the dissolved phenanthrenequinone out of the mesoporous carbon, and improves cycling performance.

SUBMITTER: Kwon MS

PROVIDER: S-EPMC4261180 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

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Synthesis of ordered mesoporous phenanthrenequinone-carbon via π-π interaction-dependent vapor pressure for rechargeable batteries.

Kwon Mi-Sook MS Choi Aram A Park Yuwon Y Cheon Jae Yeong JY Kang Hyojin H Jo Yong Nam YN Kim Young-Jun YJ Hong Sung You SY Joo Sang Hoon SH Yang Changduk C Lee Kyu Tae KT

Scientific reports 20141210

The π-π interaction-dependent vapour pressure of phenanthrenequinone can be used to synthesize a phenanthrenequinone-confined ordered mesoporous carbon. Intimate contact between the insulating phenanthrenequinone and the conductive carbon framework improves the electrical conductivity. This enables a more complete redox reaction take place. The confinement of the phenanthrenequinone in the mesoporous carbon mitigates the diffusion of the dissolved phenanthrenequinone out of the mesoporous carbon ...[more]

PMID: 25490893

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