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Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis.

ABSTRACT: New cyclodextrin (CD)-grafted polymers functionalized with water-soluble phosphanes were synthesized in three steps starting from polyNAS. Once characterized by NMR spectroscopy and size-exclusion chromatography, they were used as additives in Rh-catalyzed hydroformylation of 1-hexadecene. The combined supramolecular and coordinating properties of these polymers allowed increasing the catalytic activity of the reaction without affecting the selectivities.

SUBMITTER: Potier J 

PROVIDER: S-EPMC4273264 | biostudies-literature | 2014

REPOSITORIES: biostudies-literature

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Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis.

Potier Jonathan J   Menuel Stéphane S   Mathiron David D   Bonnet Véronique V   Hapiot Frédéric F   Monflier Eric E  

Beilstein journal of organic chemistry 20141111

New cyclodextrin (CD)-grafted polymers functionalized with water-soluble phosphanes were synthesized in three steps starting from polyNAS. Once characterized by NMR spectroscopy and size-exclusion chromatography, they were used as additives in Rh-catalyzed hydroformylation of 1-hexadecene. The combined supramolecular and coordinating properties of these polymers allowed increasing the catalytic activity of the reaction without affecting the selectivities. ...[more]

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