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Photoinduced heterodisulfide metathesis for reagent-free synthesis of polymer nanoparticles.


ABSTRACT: Reagent-free synthetic methods are of great interest because of their simplicity and implications in green chemistry. We have taken advantage of photoinduced heterodisulfide metathesis to generate crosslinked polymer nanoparticles. The method of development and the mechanistic basis for the synthetic approach are outlined in this communication.

SUBMITTER: Li L 

PROVIDER: S-EPMC4282922 | biostudies-literature | 2015 Jan

REPOSITORIES: biostudies-literature

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Photoinduced heterodisulfide metathesis for reagent-free synthesis of polymer nanoparticles.

Li Longyu L   Song Cunfeng C   Jennings Matthew M   Thayumanavan S S  

Chemical communications (Cambridge, England) 20150101 8


Reagent-free synthetic methods are of great interest because of their simplicity and implications in green chemistry. We have taken advantage of photoinduced heterodisulfide metathesis to generate crosslinked polymer nanoparticles. The method of development and the mechanistic basis for the synthetic approach are outlined in this communication. ...[more]

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