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Synthesis of enaminones and their difluoroboron complexes through domino aryl migration.


ABSTRACT: A new domino strategy for selective synthesis of enaminones and their difluoroboron complexes through aryl migration has been developed. The reaction features low-cost and readily accessible starting materials, reliable scalability, and bond-forming efficiency as well as simple one-pot operation, which makes this strategy highly viable for future applications.

SUBMITTER: Yang Z 

PROVIDER: S-EPMC4309928 | biostudies-literature | 2015 Jan

REPOSITORIES: biostudies-literature

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Synthesis of enaminones and their difluoroboron complexes through domino aryl migration.

Yang Zheng Z   Jiang Bo B   Hao Wen-Juan WJ   Zhou Peng P   Tu Shu-Jiang SJ   Li Guigen G  

Chemical communications (Cambridge, England) 20150101 7


A new domino strategy for selective synthesis of enaminones and their difluoroboron complexes through aryl migration has been developed. The reaction features low-cost and readily accessible starting materials, reliable scalability, and bond-forming efficiency as well as simple one-pot operation, which makes this strategy highly viable for future applications. ...[more]

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