Redox active dendronized polystyrenes equipped with peripheral triarylamines.
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ABSTRACT:
SUBMITTER: Nokami T
PROVIDER: S-EPMC4311719 | biostudies-literature | 2014
REPOSITORIES: biostudies-literature
Publications
Redox active dendronized polystyrenes equipped with peripheral triarylamines.
Nokami Toshiki T Musya Naoki N Morofuji Tatsuya T Takeda Keiji K Takumi Masahiro M Shimizu Akihiro A Yoshida Jun-Ichi J
Beilstein journal of organic chemistry 20141222
Dendronized polystyrene having peripheral bromo groups was prepared from the dendronization of unfunctionalized polystyrene with dendritic diarylcarbenium ions bearing peripheral bromo groups using the "cation pool" method. The palladium-catalyzed amination of the peripheral bromo groups with diarylamine gave dendronized polystyrene equipped with peripheral triarylamines, which exhibited two sets of reversible redox peaks in the cyclic voltammetry curves. ...[more]
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