Browse
Submit Data
Databases
API
Help

Dataset Information

30 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Sample-averaged biexciton quantum yield measured by solution-phase photon correlation.

ABSTRACT: The brightness of nanoscale optical materials such as semiconductor nanocrystals is currently limited in high excitation flux applications by inefficient multiexciton fluorescence. We have devised a solution-phase photon correlation measurement that can conveniently and reliably measure the average biexciton-to-exciton quantum yield ratio of an entire sample without user selection bias. This technique can be used to investigate the multiexciton recombination dynamics of a broad scope of synthetically underdeveloped materials, including those with low exciton quantum yields and poor fluorescence stability. Here, we have applied this method to measure weak biexciton fluorescence in samples of visible-emitting InP/ZnS and InAs/ZnS core/shell nanocrystals, and to demonstrate that a rapid CdS shell growth procedure can markedly increase the biexciton fluorescence of CdSe nanocrystals.

SUBMITTER: Beyler AP

PROVIDER: S-EPMC4346255 | biostudies-literature | 2014 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Sample-averaged biexciton quantum yield measured by solution-phase photon correlation.

Beyler Andrew P AP Bischof Thomas S TS Cui Jian J Coropceanu Igor I Harris Daniel K DK Bawendi Moungi G MG

Nano letters 20141119 12

The brightness of nanoscale optical materials such as semiconductor nanocrystals is currently limited in high excitation flux applications by inefficient multiexciton fluorescence. We have devised a solution-phase photon correlation measurement that can conveniently and reliably measure the average biexciton-to-exciton quantum yield ratio of an entire sample without user selection bias. This technique can be used to investigate the multiexciton recombination dynamics of a broad scope of syntheti ...[more]

PMID: 25409496

Similar Datasets

Biexciton quantum yield of single semiconductor nanocrystals from photon statistics.

Project description:Biexciton properties strongly affect the usability of a light emitter in quantum photon sources and lasers but are difficult to measure for single fluorophores at room temperature due to luminescence intermittency and bleaching at the high excitation fluences usually required. Here, we observe the biexciton (BX) to exciton (X) to ground photoluminescence cascade of single colloidal semiconductor nanocrystals (NCs) under weak excitation in a g((2)) photon correlation measurement and show that the normalized amplitude of the cascade feature is equal to the ratio of the BX to X fluorescence quantum yields. This imposes a limit on the attainable depth of photon antibunching and provides a robust means to study single emitter biexciton physics. In NC samples, we show that the BX quantum yield is considerably inhomogeneous, consistent with the defect sensitivity expected of the Auger nonradiative recombination mechanism. The method can be extended to study X,BX spectral and polarization correlations.

| S-EPMC3278281 | biostudies-literature

Biexciton quantum yield heterogeneities in single CdSe (CdS) core (shell) nanocrystals and its correlation to exciton blinking.

Project description:We explore biexciton (BX) nonradiative recombination processes in single semiconductor nanocrystals (NCs) using confocal fluorescence microscopy and second-order photon intensity correlation. More specifically, we measure the photoluminescence blinking and BX quantum yields (QYs) and study the correlation between these two measurements for single core (shell) CdSe (CdS) nanocrystals (NCs). We find that NCs with a high "on" time fraction are significantly more likely to have a high BX QY than NCs with a low "on" fraction, even though the BX QYs of NCs with a high "on" fraction vary dramatically. The BX QYs of single NCs are also weakly dependent upon excitation wavelength. The weak correlation between exciton "on" fractions and BX QYs suggests that multiple recombination processes are involved in the BX recombination. To explain our results, we propose a model that combines both trapping and an Auger mechanism for BX recombination.

| S-EPMC3482465 | biostudies-literature

Photon Correlation Spectroscopy of Luminescent Quantum Defects in Carbon Nanotubes.

Project description:Defect-decorated single-wall carbon nanotubes have shown rapid growing potential for imaging, sensing, and the development of room-temperature single-photon sources. The key to the highly nonclassical emission statistics is the discrete energy spectrum of defect-localized excitons. However, variations in defect configurations give rise to distinct spectral bands that may compromise single-photon efficiency and purity in practical devices, and experimentally it has been challenging to study the exciton population distribution among the various defect-specific states. Here, we performed photon correlation spectroscopy on hexyl-decorated single-wall carbon nanotubes to unravel the dynamics and competition between neutral and charged exciton populations. With autocorrelation measurements at the single-tube level, we prove the nonclassical photon emission statistics of defect-specific exciton and trion photoluminescence and identify their mutual exclusiveness in photoemissive events with cross-correlation spectroscopy. Moreover, our study reveals the presence of a dark state with population-shelving time scales between 10 and 100 ns. These new insights will guide further development of chemically tailored carbon nanotube states for quantum photonics applications.

| S-EPMC6814285 | biostudies-literature

Quantum metrology with parametric amplifier-based photon correlation interferometers.

Project description:Conventional interferometers usually utilize beam splitters for wave splitting and recombination. These interferometers are widely used for precision measurement. Their sensitivity for phase measurement is limited by the shot noise, which can be suppressed with squeezed states of light. Here we study a new type of interferometer in which the beam splitting and recombination elements are parametric amplifiers. We observe an improvement of 4.1±0.3 dB in signal-to-noise ratio compared with a conventional interferometer under the same operating condition, which is a 1.6-fold enhancement in rms phase measurement sensitivity beyond the shot noise limit. The improvement is due to signal enhancement. Combined with the squeezed state technique for shot noise suppression, this interferometer promises further improvement in sensitivity. Furthermore, because nonlinear processes are involved in this interferometer, we can couple a variety of different waves and form new types of hybrid interferometers, opening a door for many applications in metrology.

| S-EPMC3916837 | biostudies-other

Surface passivation extends single and biexciton lifetimes of InP quantum dots.

Project description:Indium phosphide quantum dots (InP QDs) are nontoxic nanomaterials with potential applications in photocatalytic and optoelectronic fields. Post-synthetic treatments of InP QDs are known to be essential for improving their photoluminescence quantum efficiencies (PLQEs) and device performances, but the mechanisms remain poorly understood. Herein, by applying ultrafast transient absorption and photoluminescence spectroscopies, we systematically investigate the dynamics of photogenerated carriers in InP QDs and how they are affected by two common passivation methods: HF treatment and the growth of a heterostructure shell (ZnS in this study). The HF treatment is found to improve the PLQE up to 16-20% by removing an intrinsic fast hole trapping channel (τ h,non = 3.4 ± 1 ns) in the untreated InP QDs while having little effect on the band-edge electron decay dynamics (τ e = 26-32 ns). The growth of the ZnS shell, on the other hand, is shown to improve the PLQE up to 35-40% by passivating both electron and hole traps in InP QDs, resulting in both a long-lived band-edge electron (τ e > 120 ns) and slower hole trapping lifetime (τ h,non > 45 ns). Furthermore, both the untreated and the HF-treated InP QDs have short biexciton lifetimes (τ xx ∼ 1.2 ± 0.2 ps). The growth of an ultra-thin ZnS shell (∼0.2 nm), on the other hand, can significantly extend the biexciton lifetime of InP QDs to 20 ± 2 ps, making it a passivation scheme that can improve both the single and multiple exciton lifetimes. Based on these results, we discuss the possible trap-assisted Auger processes in InP QDs, highlighting the particular importance of trap passivation for reducing the Auger recombination loss in InP QDs.

| S-EPMC7416692 | biostudies-literature

Membrane-protein binding measured with solution-phase plasmonic nanocube sensors.

Project description:We describe a solution-phase sensor of lipid-protein binding based on localized surface plasmon resonance (LSPR) of silver nanocubes. When silica-coated nanocubes are mixed in a suspension of lipid vesicles, supported membranes spontaneously assemble on their surfaces. Using a standard laboratory spectrophotometer, we calibrated the LSPR peak shift due to protein binding to the membrane surface and then characterized the lipid-binding specificity of a pleckstrin homology domain protein.

| S-EPMC3703907 | biostudies-literature

Biexciton Binding Energy and Line width of Single Quantum Dots at Room Temperature.

Project description:Broadening of multiexciton emission from colloidal quantum dots (QDs) at room temperature is important for their use in high-power applications, but an in-depth characterization has not been possible until now. We present and apply a novel spectroscopic method to quantify the biexciton line width and biexciton binding energy of single CdSe/CdS/ZnS colloidal QDs at room temperature. In our method, which we term "cascade spectroscopy", we select emission events from the biexciton cascade and reconstruct their spectrum. The biexciton has an average emission line width of 86 meV on the single-QD scale, similar to that of the exciton. Variations in the biexciton repulsion (Eb = 4.0 ± 3.1 meV; mean ± standard deviation of 15 QDs) are correlated with but are more narrowly distributed than variations in the exciton energy (10.0 meV standard deviation). Using a simple quantum-mechanical model, we conclude that inhomogeneous broadening in our sample is primarily due to variations in the CdS shell thickness.

| S-EPMC8283756 | biostudies-literature

High yield and ultrafast sources of electrically triggered entangled-photon pairs based on strain-tunable quantum dots.

Project description:Triggered sources of entangled photon pairs are key components in most quantum communication protocols. For practical quantum applications, electrical triggering would allow the realization of compact and deterministic sources of entangled photons. Entangled-light-emitting-diodes based on semiconductor quantum dots are among the most promising sources that can potentially address this task. However, entangled-light-emitting-diodes are plagued by a source of randomness, which results in a very low probability of finding quantum dots with sufficiently small fine structure splitting for entangled-photon generation (∼10(-2)). Here we introduce strain-tunable entangled-light-emitting-diodes that exploit piezoelectric-induced strains to tune quantum dots for entangled-photon generation. We demonstrate that up to 30% of the quantum dots in strain-tunable entangled-light-emitting-diodes emit polarization-entangled photons. An entanglement fidelity as high as 0.83 is achieved with fast temporal post selection. Driven at high speed, that is 400 MHz, strain-tunable entangled-light-emitting-diodes emerge as promising devices for high data-rate quantum applications.

| S-EPMC4686767 | biostudies-literature

Ultrabright Au@Cu14 nanoclusters: 71.3% phosphorescence quantum yield in non-degassed solution at room temperature.

Project description:The photoluminescence of metal nanoclusters is typically low, and phosphorescence emission is rare due to ultrafast free-electron dynamics and quenching by phonons. Here, we report an electronic engineering approach to achieving very high phosphorescence (quantum yield 71.3%) from a [Au@Cu14(SPh t Bu)12(PPh(C2H4CN)2)6]+ nanocluster (abbreviated Au@Cu14 ) in non-degassed solution at room temperature. The structure of Au@Cu14 has a single-Au-atom kernel, which is encapsulated by a rigid Cu(I) complex cage. This core-shell structure leads to highly efficient singlet-to-triplet intersystem crossing and suppression of nonradiative energy loss. Unlike the phosphorescent organic materials and organometallic complexes-which require de-aerated conditions due to severe quenching by air (i.e., O2)-the phosphorescence from Au@Cu14 is much less sensitive to air, which is important for lighting and biomedical applications.

| S-EPMC7787487 | biostudies-literature

Determining the Photoisomerization Quantum Yield of Photoswitchable Molecules in Solution and in the Solid State.

Project description:Photoswitchable molecules are able to isomerize between two metastable forms through light stimuli. Originally being studied by photochemists, this type of molecule has now found a wide range of applications within physics, chemistry and biology. The extensive usage of photochromic molecules is due to the two isomers having fundamentally different physical and chemical properties. The most important attribute of a photoswitch is the photoisomerization quantum yield, which defines the efficiency of the photoisomerization event. Here we show how to determine the photoisomerization quantum yield in the solid state and in solution when taking thermal processes into account. The described method together with provided software allows for rapid and accurate determination of the isomerization process for this important class of molecules.

| S-EPMC5259717 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data