Ontology highlight
ABSTRACT:
SUBMITTER: Czakler M
PROVIDER: S-EPMC4362471 | biostudies-literature | 2014 Apr
REPOSITORIES: biostudies-literature
Czakler Matthias M Artner Christine C Schubert Ulrich U
European journal of inorganic chemistry 20140311 12
New phosphonate/acetate-substituted titanium oxo/alkoxo clusters were prepared from Ti(O<i>i</i>Pr)<sub>4</sub> and bis(trimethylsilyl) phosphonates in the presence of acetic acid, which served to generate water in situ through ester formation. The process led to clusters with a higher degree of condensation than in previously known phosphonate-substituted titanium oxo clusters. The clusters [Ti<sub>6</sub>O<sub>4</sub>(O<i>i</i>Pr)<sub>10</sub>(OAc)<sub>2</sub>(O<sub>3</sub>PR)<sub>2</sub>] (OA ...[more]