Ontology highlight
ABSTRACT:
SUBMITTER: Janek M
PROVIDER: S-EPMC6164694 | biostudies-literature | 2018 Sep
REPOSITORIES: biostudies-literature
Janek Maciej M Radtke Aleksandra A Muzioł Tadeusz M TM Jerzykiewicz Maria M Piszczek Piotr P
Materials (Basel, Switzerland) 20180908 9
Titanium(IV) oxo-clusters of the general formula (Ti₄O₂(O<sup>i</sup>Bu)<sub>10</sub>(O₂CR')₂) (R' = C<sub>13</sub>H₉ (<b>1</b>), PhCl (<b>2</b>), PhNO₂ (<b>3</b>)) were studied in order to estimate their potential photoactivity. The structure of the resulting tetranuclear Ti(IV) oxo-complexes was then determined via single crystal X-ray diffraction, infrared and Raman spectroscopy, and electron spin resonance (ESR). An analysis of diffuse reflectance spectra (DRS) allowed for the assessment of ...[more]