Ontology highlight
ABSTRACT:
SUBMITTER: Sam B
PROVIDER: S-EPMC4405479 | biostudies-literature | 2015 Apr
REPOSITORIES: biostudies-literature
Sam Brannon B Luong Tom T Krische Michael J MJ
Angewandte Chemie (International ed. in English) 20150310 18
Ruthenium(II) complexes catalyze the CC coupling of 1,1-disubstituted allenes and fluorinated alcohols to form homoallylic alcohols bearing all-carbon quaternary centers with good to complete levels of diastereoselectivity. Whereas fluorinated alcohols are relatively abundant and tractable, the corresponding aldehydes are often not commercially available because of their instability. ...[more]