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Large-area formation of self-aligned crystalline domains of organic semiconductors on transistor channels using CONNECT.


ABSTRACT: The electronic properties of solution-processable small-molecule organic semiconductors (OSCs) have rapidly improved in recent years, rendering them highly promising for various low-cost large-area electronic applications. However, practical applications of organic electronics require patterned and precisely registered OSC films within the transistor channel region with uniform electrical properties over a large area, a task that remains a significant challenge. Here, we present a technique termed "controlled OSC nucleation and extension for circuits" (CONNECT), which uses differential surface energy and solution shearing to simultaneously generate patterned and precisely registered OSC thin films within the channel region and with aligned crystalline domains, resulting in low device-to-device variability. We have fabricated transistor density as high as 840 dpi, with a yield of 99%. We have successfully built various logic gates and a 2-bit half-adder circuit, demonstrating the practical applicability of our technique for large-scale circuit fabrication.

SUBMITTER: Park S 

PROVIDER: S-EPMC4426406 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature

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Large-area formation of self-aligned crystalline domains of organic semiconductors on transistor channels using CONNECT.

Park Steve S   Giri Gaurav G   Shaw Leo L   Pitner Gregory G   Ha Jewook J   Koo Ja Hoon JH   Gu Xiaodan X   Park Joonsuk J   Lee Tae Hoon TH   Nam Ji Hyun JH   Hong Yongtaek Y   Bao Zhenan Z  

Proceedings of the National Academy of Sciences of the United States of America 20150420 18


The electronic properties of solution-processable small-molecule organic semiconductors (OSCs) have rapidly improved in recent years, rendering them highly promising for various low-cost large-area electronic applications. However, practical applications of organic electronics require patterned and precisely registered OSC films within the transistor channel region with uniform electrical properties over a large area, a task that remains a significant challenge. Here, we present a technique term  ...[more]

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