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Diastereoselective Ni-catalyzed 1,4-hydroboration of chiral dienols.

ABSTRACT: The Ni-catalyzed hydroboration of dienols occurs in a 1,4 fashion and delivers a syn-propionate motif in high diastereoselectivity and with a stereodefined trisubstituted crotylboronic ester. The boronic ester can be further manipulated to provide carbon-carbon or carbon-oxygen bonds.

SUBMITTER: Ely RJ 

PROVIDER: S-EPMC4444069 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

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Diastereoselective Ni-catalyzed 1,4-hydroboration of chiral dienols.

Ely Robert J RJ   Yu Zhiyong Z   Morken James P JP  

Tetrahedron letters 20150601 23

The Ni-catalyzed hydroboration of dienols occurs in a 1,4 fashion and delivers a syn-propionate motif in high diastereoselectivity and with a stereodefined trisubstituted crotylboronic ester. The boronic ester can be further manipulated to provide carbon-carbon or carbon-oxygen bonds. ...[more]

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