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Crystal structure of 4-benzamido-2-hy-droxy-benzoic acid.

ABSTRACT: In the title compound, C14H11NO4, the dihedral angle between the mean planes of the aromatic rings is 3.96?(12)° and an intra-molecular O-H?O hydrogen bond closes an S(6) ring. A short intra-molecular C-H?O contact is also seen. In the crystal, carb-oxy-lic acid inversion dimers linked by pairs of O-H?O hydrogen bonds generate R 2 (2)(8) loops. Conversely, the N-H group does not form a hydrogen bond. Aromatic ?-? inter-actions exist at a centroid-centroid distance of 3.8423?(15)?Å between the benzene rings. An extremely weak C-H?? inter-action also is present.

SUBMITTER: Shahid M

PROVIDER: S-EPMC4459298 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

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Crystal structure of 4-benzamido-2-hy-droxy-benzoic acid.

Shahid Muhammad M Choudhary Muhammad Aziz MA Butt Arshad Farooq AF Tahir Muhammad Nawaz MN Salim Muhammad M

Acta crystallographica. Section E, Crystallographic communications 20150520 Pt 6

In the title compound, C14H11NO4, the dihedral angle between the mean planes of the aromatic rings is 3.96 (12)° and an intra-molecular O-H⋯O hydrogen bond closes an S(6) ring. A short intra-molecular C-H⋯O contact is also seen. In the crystal, carb-oxy-lic acid inversion dimers linked by pairs of O-H⋯O hydrogen bonds generate R 2 (2)(8) loops. Conversely, the N-H group does not form a hydrogen bond. Aromatic π-π inter-actions exist at a centroid-centroid distance of 3.8423 (15) Å between the be ...[more]

PMID: 26090194

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