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Crystal structure of (2-chloro-eth-yl)[2-(methyl-sulfan-yl)benz-yl]ammonium chloride.

ABSTRACT: In the title mol-ecular salt, C10H15ClNS(+)·Cl(-), the cation is [R'R"NH2](+), where R' is 2-MeS-C6H4CH2- and R" is -CH2CH2Cl, and the anion is Cl(-). In the cation, the N atom is protonated with sp (3)-hybridization and with a tetra-hedral geometry. In the crystal, the anions are connected to the cations through two pairs of N-H?Cl hydrogen bonds, generating a four-centred inversion dimer with an R 4 (2)(8) ring motif.

SUBMITTER: Raghavendra Kumar P

PROVIDER: S-EPMC4459316 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

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Crystal structure of (2-chloro-eth-yl)[2-(methyl-sulfan-yl)benz-yl]ammonium chloride.

Raghavendra Kumar P P Shailesh Upereti U Palakshamurthy B S BS

Acta crystallographica. Section E, Crystallographic communications 20150513 Pt 6

In the title mol-ecular salt, C10H15ClNS(+)·Cl(-), the cation is [R'R"NH2](+), where R' is 2-MeS-C6H4CH2- and R" is -CH2CH2Cl, and the anion is Cl(-). In the cation, the N atom is protonated with sp (3)-hybridization and with a tetra-hedral geometry. In the crystal, the anions are connected to the cations through two pairs of N-H⋯Cl hydrogen bonds, generating a four-centred inversion dimer with an R 4 (2)(8) ring motif. ...[more]

PMID: 26090135

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