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Well-defined palladium nanoparticles supported on siliceous mesocellular foam as heterogeneous catalysts for the oxidation of water.

ABSTRACT: Herein, we describe the use of Pd nanoparticles immobilized on an amino-functionalized siliceous mesocellular foam for the catalytic oxidation of H2O. The Pd nanocatalyst proved to be capable of mediating the four-electron oxidation of H2O to O2, both chemically and photochemically. The Pd nanocatalyst is easy to prepare and shows high chemical stability, low leaching, and recyclability. Together with its promising catalytic activity, these features make the Pd nanocatalyst of potential interest for future sustainable solar-fuel production.

SUBMITTER: Verho O

PROVIDER: S-EPMC4464534 | biostudies-literature | 2015 Apr

REPOSITORIES: biostudies-literature

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Well-defined palladium nanoparticles supported on siliceous mesocellular foam as heterogeneous catalysts for the oxidation of water.

Verho Oscar O Åkermark Torbjörn T Johnston Eric V EV Gustafson Karl P J KP Tai Cheuk-W CW Svengren Henrik H Kärkäs Markus D MD Bäckvall Jan-E JE Åkermark Björn B

Chemistry (Weinheim an der Bergstrasse, Germany) 20150316 15

Herein, we describe the use of Pd nanoparticles immobilized on an amino-functionalized siliceous mesocellular foam for the catalytic oxidation of H2O. The Pd nanocatalyst proved to be capable of mediating the four-electron oxidation of H2O to O2, both chemically and photochemically. The Pd nanocatalyst is easy to prepare and shows high chemical stability, low leaching, and recyclability. Together with its promising catalytic activity, these features make the Pd nanocatalyst of potential interest ...[more]

PMID: 25777800

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