Ontology highlight
ABSTRACT:
SUBMITTER: Sung S
PROVIDER: S-EPMC4471577 | biostudies-literature | 2015 May
REPOSITORIES: biostudies-literature
Sung Simon S Braddock D Christopher DC Armstrong Alan A Brennan Colin C Sale David D White Andrew J P AJ Davies Robert P RP
Chemistry (Weinheim an der Bergstrasse, Germany) 20150318 19
A series of copper(I) alkylamide complexes have been synthesised; copper(I) dicyclohexylamide (1), copper(I) 2,2,6,6-tetramethylpiperidide (2), copper(I) pyrrolidide (3), copper(I) piperidide (4), and copper(I) benzylamide (5). Their solid-state structures and structures in [D6 ]benzene solution are characterised, with the aggregation state in solution determined by a combination of DOSY NMR spectroscopy and DFT calculations. Complexes 1, 2 and 4 are shown to exist as tetramers in the solid stat ...[more]