Ontology highlight
ABSTRACT:
SUBMITTER: Garcia A
PROVIDER: S-EPMC4480982 | biostudies-literature | 2015 Mar
REPOSITORIES: biostudies-literature
Garcia Angie A Otte Douglas A L DA Salamant Walter A WA Sanzone Jillian R JR Woerpel K A KA
Angewandte Chemie (International ed. in English) 20150122 10
In contrast to observations with carbohydrates, experiments with 4-alkoxy-substituted acetals indicate that an alkoxy group can accelerate acetal hydrolysis by up to 20-fold compared to substrates without an alkoxy group. The acceleration of ionization in more flexible acetals can be up to 200-fold when compensated for inductive effects. ...[more]