Biosynthesis of the C15-acetogenin laurepoxide may involve bromine-induced skeletal rearrangement of a ?4-oxocene precursor.
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ABSTRACT:
SUBMITTER: Taylor MT
PROVIDER: S-EPMC4489422 | biostudies-literature | 2015 Jun
REPOSITORIES: biostudies-literature
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Biosynthesis of the C15-acetogenin laurepoxide may involve bromine-induced skeletal rearrangement of a Δ4-oxocene precursor.
Taylor Michael T MT Fox Joseph M JM
Tetrahedron letters 20150601 23
An electrophilic bromine catalyzed skeletal rearrangement of an Δ4-oxocene to an epoxy furan has been described. This skeletal rearrangement suggests a plausible mechanism for the biosynthesis of the C15-acetogenin laurepoxide. ...[more]
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