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Nitrite-templated synthesis of lanthanide-containing [2]rotaxanes for anion sensing.


ABSTRACT: The first anion-templated synthesis of a lanthanide-containing interlocked molecule is demonstrated by utilizing a nitrite anion to template initial pseudorotaxane formation. Subsequent stoppering of the interpenetrated assembly allows for the preparation of a lanthanide-functionalized [2]rotaxane in high yield. Following removal of the nitrite anion template, the europium [2]rotaxane host is demonstrated to recognize and sense fluoride selectively.

SUBMITTER: Langton MJ 

PROVIDER: S-EPMC4497609 | biostudies-literature | 2014 Oct

REPOSITORIES: biostudies-literature

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