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Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization.

ABSTRACT: Carbon dioxide utilisation (CDU) is currently gaining increased interest due to the abundance of CO₂ and its possible application as a C₁ building block. We herein report the first example of atmospheric pressure carbon dioxide incorporation into oxetane to selectively form trimethylene carbonate (TMC), which is a significant challenge as TMC is thermodynamically less favoured than its corresponding co-polymer.

SUBMITTER: Buckley BR

PROVIDER: S-EPMC4502766 | biostudies-literature | 2015 Jan

REPOSITORIES: biostudies-literature

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Selective Formation of Trimethylene Carbonate (TMC): Atmospheric Pressure Carbon Dioxide Utilization.

Buckley Benjamin R BR Patel Anish P AP Wijayantha K G Upul KG

European journal of organic chemistry 20141210 3

Carbon dioxide utilisation (CDU) is currently gaining increased interest due to the abundance of CO2 and its possible application as a C1 building block. We herein report the first example of atmospheric pressure carbon dioxide incorporation into oxetane to selectively form trimethylene carbonate (TMC), which is a significant challenge as TMC is thermodynamically less favoured than its corresponding co-polymer. ...[more]

PMID: 26213485

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