Ontology highlight
ABSTRACT:
SUBMITTER: Edwards JA
PROVIDER: S-EPMC4555408 | biostudies-literature | 2015 Sep
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20150806 Pt 9
The title compound, [Re6Se8{O3SC6H4(CH3)}{P(C2H5)3}5](CH3C6H4SO3)·2CH2Cl2, contains the face-capped hexa-nuclear [Re6(μ3-Se)8](2+) cluster core. The [Re6Se8](2+) cluster core displays a non-crystallographic center of symmetry and is bonded through the Re(III) atoms to five tri-ethyl-phosphane ligands and one p-toluene-sulfonate ligand. One p-toluene-sulfonate counter-ion and two di-chloro-methane solvent mol-ecules are also present in the asymmetric unit. One of the ethyl chains of one triethylp ...[more]