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Trans-Bis(?-benzene-thiol-ato-?(2) S:S)bis[chlorido-(tri-phenyl-phosphane-?P)palladium(II)] chloro-form disolvate.

ABSTRACT: The title compound, [Pd2Cl2(C6H5S)2(C18H15P)2]·2CHCl3, contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzene-thiol-ate ligands with different Pd-S distances [2.2970?(11) and 2.3676?(11)?Å]. The coordination of the metal atom is completed by a chloride anion [2.3383?(11)?Å] and a tri-phenyl-phosphane ligand [2.2787?(11)?Å]. Weak C-H?Cl inter-actions are present between complex mol-ecules and the CHCl3 solvent mol-ecule. The latter is disordered over two positions in a 0.792?(8):0.208?(8) ratio. The crystal under investigation was found to be twinned by nonmerohedry, with a fraction of 73.4?(1)% for the major twin component.

SUBMITTER: Avila-Sorrosa A

PROVIDER: S-EPMC3793701 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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trans-Bis(μ-benzene-thiol-ato-κ(2) S:S)bis[chlorido-(tri-phenyl-phosphane-κP)palladium(II)] chloro-form disolvate.

Avila-Sorrosa Alcives A Reyes-Arellano Alicia A Germán-Acacio Juan Manuel JM Reyes-Martínez Reyna R Morales-Morales David D

Acta crystallographica. Section E, Structure reports online 20130724 Pt 8

The title compound, [Pd2Cl2(C6H5S)2(C18H15P)2]·2CHCl3, contains a centrosymmetric dinuclear palladium complex with the Pd(II) cation in a slightly distorted square-planar coordination environment. The Pd(II) cations are bridged by the S atoms of two benzene-thiol-ate ligands with different Pd-S distances [2.2970 (11) and 2.3676 (11) Å]. The coordination of the metal atom is completed by a chloride anion [2.3383 (11) Å] and a tri-phenyl-phosphane ligand [2.2787 (11) Å]. Weak C-H⋯Cl inter-actions ...[more]

PMID: 24109288

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