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Crystal structure of tetrakis-(acetyl-acetonato)di-chloridodi-?3-methano-lato-tetra-?2-methano-lato-tetra-iron(III).

ABSTRACT: The title complex, [Fe4(C5H7O2)4(CH3O)6Cl2] or [Fe4(acac)4(?2-OMe)4(?3-OMe)2Cl2] (acac = acetyl-acetonate), crystallizes in the ortho-rhom-bic Pbca space group with one half of the mol-ecule per asymmetric unit, the other half being completed by inversion symmetry. The core structure consists of a face-sharing double pseudo-cubane entity with two opposite corners missing. Weak C-H?Cl inter-molecular inter-actions result in a two-dimensional layered structure parallel to the ac plane.

SUBMITTER: Richers CP

PROVIDER: S-EPMC4571370 | biostudies-literature | 2015 Aug

REPOSITORIES: biostudies-literature

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Crystal structure of tetrakis-(acetyl-acetonato)di-chloridodi-μ3-methano-lato-tetra-μ2-methano-lato-tetra-iron(III).

Richers Casseday P CP Bertke Jeffery A JA Gray Danielle L DL Rauchfuss Thomas B TB

Acta crystallographica. Section E, Crystallographic communications 20150729 Pt 8

The title complex, [Fe4(C5H7O2)4(CH3O)6Cl2] or [Fe4(acac)4(μ2-OMe)4(μ3-OMe)2Cl2] (acac = acetyl-acetonate), crystallizes in the ortho-rhom-bic Pbca space group with one half of the mol-ecule per asymmetric unit, the other half being completed by inversion symmetry. The core structure consists of a face-sharing double pseudo-cubane entity with two opposite corners missing. Weak C-H⋯Cl inter-molecular inter-actions result in a two-dimensional layered structure parallel to the ac plane. ...[more]

PMID: 26396769

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