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ABSTRACT:
SUBMITTER: Zaleski DP
PROVIDER: S-EPMC4578364 | biostudies-literature | 2015 Mar
REPOSITORIES: biostudies-literature
Zaleski Daniel P DP Tew David P DP Walker Nicholas R NR Legon Anthony C AC
The journal of physical chemistry. A 20150310 12
The new linear molecule Ag-C≡C-Cl has been detected and fully characterized by means of rotational spectroscopy. It was synthesized by laser ablation of a silver rod in the presence of a gaseous sample containing a low concentration of CCl4 in argon, cooled to a rotational temperature approaching ∼1-3 K through supersonic expansion, and analyzed by chirped-pulse, Fourier transform microwave spectroscopy. Six isotopologues were investigated, and for each the spectroscopic constants B0, D(J) and χ ...[more]