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Phosphate Tether-Mediated Ring-Closing Metathesis for the Generation of Medium to Large, P-Stereogenic Bicyclo[n.3.1]phosphates.


ABSTRACT: A phosphate tether-mediated ring-closing metathesis study towards the synthesis of P-stereogenic bicyclo[6.3.1]-, bicyclo[7.3.1]-, and bicyclo[8.3.1]phosphates is reported. This study demonstrates expanded utility of phosphate tether-mediated desymmetrization of C2-symmetric, 1,3-anti-diol dienes in generating complex medium to large, P-stereogenic bicyclo[n.3.1]phosphates..

SUBMITTER: Maitra S 

PROVIDER: S-EPMC4584409 | biostudies-literature | 2015 Sep

REPOSITORIES: biostudies-literature

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Phosphate Tether-Mediated Ring-Closing Metathesis for the Generation of Medium to Large, <i>P</i>-Stereogenic Bicyclo[n.3.1]phosphates.

Maitra Soma S   Markley Jana L JL   Chegondi Rambabu R   Hanson Paul R PR  

Tetrahedron 20150901 35


A phosphate tether-mediated ring-closing metathesis study towards the synthesis of <i>P</i>-stereogenic bicyclo[6.3.1]-, bicyclo[7.3.1]-, and bicyclo[8.3.1]phosphates is reported. This study demonstrates expanded utility of phosphate tether-mediated desymmetrization of <i>C</i><sub>2</sub>-symmetric, 1,3-<i>anti</i>-diol dienes in generating complex medium to large, <i>P</i>-stereogenic bicyclo[n.3.1]phosphates.. ...[more]

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