Ontology highlight
ABSTRACT:
SUBMITTER: Maitra S
PROVIDER: S-EPMC4584409 | biostudies-literature | 2015 Sep
REPOSITORIES: biostudies-literature
Maitra Soma S Markley Jana L JL Chegondi Rambabu R Hanson Paul R PR
Tetrahedron 20150901 35
A phosphate tether-mediated ring-closing metathesis study towards the synthesis of <i>P</i>-stereogenic bicyclo[6.3.1]-, bicyclo[7.3.1]-, and bicyclo[8.3.1]phosphates is reported. This study demonstrates expanded utility of phosphate tether-mediated desymmetrization of <i>C</i><sub>2</sub>-symmetric, 1,3-<i>anti</i>-diol dienes in generating complex medium to large, <i>P</i>-stereogenic bicyclo[n.3.1]phosphates.. ...[more]