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Crystal structure of new organically templated copper sulfate with 2-amino-pyridinium.

ABSTRACT: The title compound, (C5H7N2)2[Cu(H2O)6](SO4)2·4H2O [systematic name: bis(2-aminopyridinium) hexaaquacopper(II) bis(sulfate) tetrahydrate], comprises axially elongated hexa-aqua-coordinated octa-hedral Cu(II) ions located on an inversion centre, non-coordinating sulfate anions, 2-amino-pyridinium cations and lattice water mol-ecules. The crystal structure is built of successive inorganic and organic layers extending parallel to (001) that are connected by an extensive three-dimensional hydrogen-bonded network of the type O-H?O and N-H?O, as well as ?-? inter-actions [centroid-centroid distance 3.4140?(14)?Å, offset 0.277?Å].

SUBMITTER: Lukianova TJ

PROVIDER: S-EPMC4645056 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of new organically templated copper sulfate with 2-amino-pyridinium.

Lukianova Tamara J TJ Kinzhybalo Vasyl V Pietraszko Adam A

Acta crystallographica. Section E, Crystallographic communications 20151010 Pt 11

The title compound, (C5H7N2)2[Cu(H2O)6](SO4)2·4H2O [systematic name: bis(2-aminopyridinium) hexaaquacopper(II) bis(sulfate) tetrahydrate], comprises axially elongated hexa-aqua-coordinated octa-hedral Cu(II) ions located on an inversion centre, non-coordinating sulfate anions, 2-amino-pyridinium cations and lattice water mol-ecules. The crystal structure is built of successive inorganic and organic layers extending parallel to (001) that are connected by an extensive three-dimensional hydrogen-b ...[more]

PMID: 26594528

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