Ontology highlight
ABSTRACT:
SUBMITTER: Rajkumar MA
PROVIDER: S-EPMC4384627 | biostudies-literature | 2015 Feb
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20150131 Pt 2
The title mol-ecular salt, C5H6N3O2 (+) ·H2NO3S(-), was obtained from the reaction of sulfamic acid with 2-amino-5-nitro-pyridine. A proton transfer from sulfamic acid to the pyridine N atom occurred, resulting in the formation of a salt. As expected, this protonation leads to the widening of the C-N-C angle of the pyridine ring, to 122.9 (3)°, with the pyridinium ring being essentially planar (r.m.s. deviation = 0.025 Å). In the crystal, the ion pairs are joined by three N-H⋯O and one N-H⋯N hyd ...[more]