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Catalytic diastereoselective petasis reactions.

ABSTRACT: Multicomponent Petasis reactions: the first diastereoselective Petasis reaction catalyzed by chiral biphenols that enables the synthesis of syn and anti ?-amino alcohols in pure form has been developed. The reaction exploits a multicomponent approach that involves boronates, ?-hydroxy aldehydes, and amines.

SUBMITTER: Muncipinto G 

PROVIDER: S-EPMC4673970 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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Catalytic diastereoselective petasis reactions.

Muncipinto Giovanni G   Moquist Philip N PN   Schreiber Stuart L SL   Schaus Scott E SE  

Angewandte Chemie (International ed. in English) 20110712 35

Multicomponent Petasis reactions: the first diastereoselective Petasis reaction catalyzed by chiral biphenols that enables the synthesis of syn and anti β-amino alcohols in pure form has been developed. The reaction exploits a multicomponent approach that involves boronates, α-hydroxy aldehydes, and amines. ...[more]

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